119Sn and 1H NMR of the novel complexes [IrH(SnCl3)5]3- and [RhH(SnCl3)5]3-

✍ Scribed by Tetsu Yamakawa; Sumio Shinoda; Yasukazu Saito; Hiroshi Moriyama; Paul S. Pregosin

• Book ID: 102526883
• Publisher: John Wiley and Sons
• Year: 1985
• Tongue: English
• Weight: 261 KB
• Volume: 23
• Category: Article
• ISSN: 0749-1581
• DOI: 10.1002/mrc.1260230315

✦ Synopsis

New anionic complexes, [IrH(SnCl3),I3-and [Rl~H(snCl,),]~-, in which the hydride ligands are stabilized only by Snc13ligands, have been characterized by lWSn and 'H N M R spectroscopy. These pentakis SnC1,complexes are contained in catalyst solutions for the liquid-phase dehydrogenation of propan-2-01 yielding acetone and dihydrogen.