In the title salt, C~11~H~18~N~4~ ^2+^·2C~6~H~2~N~3~O~7~ ^−^·C~2~H~3~N, the dihedral angle between the imidazolium rings in the dication is 74.4 (2)°, and the benzene rings of the two independent picrate anions are almost parallel, with a dihedral angle of 12.0 (1)° between them.
1,1′-Methylenebis(naphthalen-2-amine) methanol solvate
✍ Scribed by Mahon, Andrew B. ;Craig, Donald C. ;Try, Andrew C.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 331 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C~21~H~18~N~2~·CH~4~O, the two naphthyl ring systems are arranged almost orthogonal to one another, with a dihedral angle of 89.8 (1)°.
📜 SIMILAR VOLUMES
In the crystal structure of the title compound, C 19 H 14 N 2 O 2 , the molecules are almost planar. The dihedral angle between the two aromatic ring systems is 3.67 (1) . ## Related literature For related literature, see: Yang et al. (2006). Experimental Crystal data C 19 H 14 N 2 O 2 M r = 302.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.015 A Ê R factor = 0.068 wR factor = 0.184 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [ZnCl~2~(C~14~H~23~N~5~)]·CH~3~OH, the Zn atom is coordinated by two N atoms and two Cl atoms in an approximately tetrahedral arrangement. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.69 (5)°. The methanol solvent molecule takes part in the formation of the