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1,1-dialkoxyalkyl alkane- and arene-carboxylates. Part II. Synthesis of dialkoxymethyl esters and of 2-acetoxy-1,3-dioxolanes

✍ Scribed by J. W. Scheeren; A. P. M. van Der Veek; W. Stevens


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
402 KB
Volume
88
Category
Article
ISSN
0165-0513

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## Abstract The synthesis of ^3^H and ^14^C labeled __d__‐2‐ethyl‐2‐phenyl‐4‐(2‐piperidyl)‐1, 3‐dioxolane hydrochloride (Va and Vb respectively) is described. The optically pure Ξ±(‐)‐2‐(2‐piperidyl)ethane‐1,2‐diol hydrochloride (II), obtained by hydrolyzing Ξ± (+)‐2,2‐diphenyl‐4‐(2‐piperidyl)‐1,3‐di