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1,1-Dialkoxyalkyl alkane- and arene-carboxylates. I.: Synthesis of dialkoxymethyl esters

โœ Scribed by J. W. Scheeren; W. Stevens


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
356 KB
Volume
85
Category
Article
ISSN
0165-0513

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Some C5 mono-and diester-substituted 1-pyrroline-1-oxides have been prepared via reductive cyclisation of the corresponding g-nitro carbonyl compounds. Ethyl 2-phenyl-1-pyrroline-1-oxide-5-carboxylate 5c was regioselectively alkylated at C5. Acylation of this molecule occurs exclusively on the nitro