10,12,12-Tris(3,3-dimethylallyl)-6,7-dihydroxy-2,2,9-trimethyl-1H-pyrano[2,3-b]anthracen-5(12H)-one
✍ Scribed by Kouam, Simeon F. ;Ngadjui, Bonaventure T. ;Choudhary, M. Iqbal ;Atta-ur-Rahman, ;Anjum, Shazia ;Ali, Shamsher
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 337 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 35 H 42 O 4 , the chromene ring is in a distorted half-chair conformation and the cyclohexadienone ring adopts a screw-boat conformation. Intramolecular O-HÁ Á ÁO hydrogen bonds involving the carbonyl and hydroxyl groups are observed.
📜 SIMILAR VOLUMES
In the molecule of the title compound, C~19~H~18~N~6~O~10~, the 2,8-dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The hinge angle of the molecule, measured as the dihedra