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10,12,12-Tris(3,3-dimethyl­allyl)-6,7-dihydr­oxy-2,2,9-trimethyl-1H-pyrano[2,3-b]anthracen-5(12H)-one

✍ Scribed by Kouam, Simeon F. ;Ngadjui, Bonaventure T. ;Choudhary, M. Iqbal ;Atta-ur-Rahman, ;Anjum, Shazia ;Ali, Shamsher


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
337 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, C 35 H 42 O 4 , the chromene ring is in a distorted half-chair conformation and the cyclohexadienone ring adopts a screw-boat conformation. Intramolecular O-HÁ Á ÁO hydrogen bonds involving the carbonyl and hydroxyl groups are observed.


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2,8-Dimethoxy-4,10-dimethyl-1,3,7,9-tetr
✍ Bhuiyan, M. Delower H. ;Jensen, Paul ;Try, Andrew C. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 488 KB

In the molecule of the title compound, C~19~H~18~N~6~O~10~, the 2,8-dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The hinge angle of the molecule, measured as the dihedra