Ethyl 12b-allyl-1-hydroxy-3,6,7,12b-tetrahydro-4H-1,3-dioxolo[4,5-g]pyrido[2,1-a]isoquinoline-2-carboxylate
✍ Scribed by Wang, Ya-Wen ;Peng, Yu
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 85 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 27 H 31 N 3 O 5 , is also known as 13oxofumitremorgin B. Intermolecular O-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds stabilize the crystal structure.
The two pyrrolidine rings in the title compound, C~25~H~22~N~2~O~6~, adopt envelope conformations. Molecules are stabilized by intramolecular O—H...O hydrogen bonds, and linked into centrosymmetric dimers by intermolecular N—H...O hydrogen bonds.
The title compound, C~26~H~23~F~2~NO~3~S, a polysubstituted piperidine enol, adopts a twisted half-chair conformation. The crystal structure is stabilized by N—H...F, C—H...O and weak C—H...π interactions. An intramolecular O—H...S interaction generates an __S__(5) graph-set motif.