10-(5-Chloro-2-hydroxybenzylidene)anthrone acetonitrile solvate
✍ Scribed by Zhou, Wei ;Yan, Jie ;Hu, Wei-Xiao ;Xia, Chun-Nian
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 101 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Zn(C 9 H 9 Br 2 NO 4 S)(C 8 H 8 N 2 )(H 2 O)]Á-C 2 H 5 OH, was synthesized in a water±ethanol solution. In the structure, one Zn atom is six-coordinated by three ligands to form the neutral complex, in which the Zn atom has a distorted octahedral coordination geometry. Molecules
The double chelate ring in the title complex, [Ni(C 15 H 11 Cl-N 3 O 3 ) 2 ]ÁC 5 H 5 N, is essentially planar, with the O,N,O-donor atoms and a pyridine ligand N atom occuping the equatorial positions in a distorted octahedral environment about the Ni atom. The NÐNiÐN axial bond angle is 173.16 (8)
In the title compound, C~26~H~24~ClN~3~O~5~S·C~2~H~3~N, the __o__-vanillin group makes dihedral angles of 25.87 (4), 11.93 (3) and 72.05 (7)° with the pyrazolone, benzene and phenyl rings, respectively. The crystal structure is stabilized by weak intermolecular C—H...O interactions that link molecul