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1-Ferrocenyl-9-oxabicyclo[3.3.1]nonan-5-ol

✍ Scribed by Fronczek, F. R. ;Cronan Jnr, J. M. ;McLaughlin, M. L.

Book ID
114504242
Publisher
International Union of Crystallography
Year
1988
Tongue
English
Weight
339 KB
Volume
44
Category
Article
ISSN
0108-2701

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## Abstract Oxymercuration of __cis__, __cis__‐1, 5‐cyclooctadiene (**1**), followed by treatment with potassium iodide and subsequent reaction with iodine, leads to six isomeric diiodides which represent the three possible stereoisomers **2**, **3**, and **4** of 2, 5‐diiodo‐9‐oxabicyclo[4.2.1]non

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## Abstract Iodine cleavage of the [3.3.1]‐iodomercuri compound **4**, easily prepared from __cis__, __cis__‐cyclooctadiene‐(1,5) by oxymercuration of the monoepoxide **1** (β†’ **3**) followed by treatment with potassium iodide, leads to three isomeric iodides **6, 7**, and **8**, the [3.3.1]‐__exo_