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1-Dichloroacetyl- t -3, t -5-dimethyl- r -2, c -6-diphenylpiperidin-4-one

✍ Scribed by Sugumar, P.; Kayalvizhi, R.; Mini, R.; Ponnuswamy, S.; Ponnuswamy, M. N.

Book ID
125468561
Publisher
International Union of Crystallography
Year
2013
Tongue
English
Weight
422 KB
Volume
69
Category
Article
ISSN
1600-5368

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The piperidine ring of the title compound, C 25 H 23 NO 2 , is in a distorted boat form. The phenyl ring at position 2 makes a dihedral angle of 80.6 (1) with the phenyl ring of the benzyl group at position 3, and 61.2 (1) with the phenyl ring at position 6. The dihedral angle between the phenyl rin

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In the title compound, C 18 H 19 N 3 O 2 ÁH 2 O, the piperidine ring adopts a distorted boat conformation. In the solid state, the molecules are linked by intermolecular O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds involving water molecules.

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The F atoms in the title compound, C 19 H 17 F 2 NO, attached to the meta positions of the two phenyl rings, are disordered with site occupancy factors of 0.5. The crystal is stabilized by strong intermolecular N-HÁ Á ÁO and van der Waals interactions.