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t-3-Methyl-1-nitroso-r-2,c-6-diphenylpiperidin-4-one oxime monohydrate

✍ Scribed by Hema, R. ;Parthasarathi, V. ;Ravikumar, K. ;Pandiarajan, K. ;Muthukumaran, G.

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 401 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805038444

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✦ Synopsis

In the title compound, C 18 H 19 N 3 O 2 ÁH 2 O, the piperidine ring adopts a distorted boat conformation. In the solid state, the molecules are linked by intermolecular O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds involving water molecules.

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The piperidine ring of the title compound, C 25 H 23 NO 2 , is in a distorted boat form. The phenyl ring at position 2 makes a dihedral angle of 80.6 (1) with the phenyl ring of the benzyl group at position 3, and 61.2 (1) with the phenyl ring at position 6. The dihedral angle between the phenyl rin

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## Abstract Thiosemicarbazones are having the ability to bind with metal and inhibit the enzyme ribonucleoside diphosphate reductase (RDR), an enzyme which is involved in the synthesis of DNA precursors in the mammalian cells. The title compound N‐methyl‐t‐3‐methyl‐r‐2, c‐6‐diphenylpiperidin‐4‐one

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t-3-Methyl-1-nitroso-r-2,c-6-diphenyl­piperidin-4-one oxime monohydrate

✦ Synopsis

t-3-Methyl-1-nitroso-r-2,c-6-diphenylpiperidin-4-one oxime monohydrate