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t-3-Benzyl-1-formyl-r-2,c-6-diphenylpiperidin-4-one

✍ Scribed by Thiruvalluvar, A. ;Balamurugan, S. ;Butcher, R. J. ;Manimekalai, A. ;Jayabharathi, J.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
508 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The piperidine ring of the title compound, C 25 H 23 NO 2 , is in a distorted boat form. The phenyl ring at position 2 makes a dihedral angle of 80.6 (1) with the phenyl ring of the benzyl group at position 3, and 61.2 (1) with the phenyl ring at position 6. The dihedral angle between the phenyl ring of the benzyl group and the phenyl ring at position 6 is 84.2 (1) . The formyl group and the phenyl ring at position 6 have equatorial orientations. The phenyl ring at position 2 and the benzyl group at position 3 have axial orientations. C-HÁ Á ÁO and C-HÁ Á Á hydrogen bonds are found in the crystal structure.

📜 SIMILAR VOLUMES

t-3-Methyl-1-nitroso-r-2,c-6-diphenyl­pi
t-3-Methyl-1-nitroso-r-2,c-6-diphenyl­piperidin-4-one oxime monohydrate
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In the title compound, C 18 H 19 N 3 O 2 ÁH 2 O, the piperidine ring adopts a distorted boat conformation. In the solid state, the molecules are linked by intermolecular O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds involving water molecules.

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Crystal structure and conformation study
Crystal structure and conformation study of N-methyl-t-3-methyl-r-2, c-6-diphenylpiperidin-4-one thiosemicarbazone
✍ N. Sampath; M. N. Ponnuswamy; M. Nethaji 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB 👁 1 views

## Abstract Thiosemicarbazones are having the ability to bind with metal and inhibit the enzyme ribonucleoside diphosphate reductase (RDR), an enzyme which is involved in the synthesis of DNA precursors in the mammalian cells. The title compound N‐methyl‐t‐3‐methyl‐r‐2, c‐6‐diphenylpiperidin‐4‐one

r-2,c-6-Bis(4-chlorophenyl)-t-3-isopropy
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The piperidine ring of the title molecule, C~20~H~21~Cl~2~NO, is in a chair form. The dihedral angle between the two benzene rings is 52.4 (1)°. The chlorophenyl and isopropyl groups have equatorial orientations. Weak C—H...O and C—H...N intramolecular interactions were found in the crystal structur

r-2,c-6-Bis(3-fluorophenyl)-t-3,t-5-dime
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The F atoms in the title compound, C 19 H 17 F 2 NO, attached to the meta positions of the two phenyl rings, are disordered with site occupancy factors of 0.5. The crystal is stabilized by strong intermolecular N-HÁ Á ÁO and van der Waals interactions.