Methyl 4-nitrophenyl ketone was brominated by copper(II) bromide in methanol; the ketone reacts with the solvent in situ to yield the title compound, C 10 H 12 BrNO 4 , which exists as a monomeric molecule.
1-Bromo-2,4-dinitrobenzene
✍ Scribed by Kruszynski, Rafal ;Czestkowski, Wojciech
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 279 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 290 K Mean '(C±C) = 0.003 A Ê R factor = 0.027 wR factor = 0.062 Data-to-parameter ratio = 11.8
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The title compound, C~7~H~3~BrNO~2~, was synthesized by the nitration of 1-bromo-2-(trifluoromethyl)benzene. In the crystal structure, there are three independent molecules, one of which lies on a crystallographic mirror plane.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.030 wR factor = 0.069 Data-to-parameter ratio = 9.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.