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1-(4-Methoxy­benz­yl)-1H-indole-3-carbaldehyde

✍ Scribed by Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A.


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
232 KB
Volume
62
Category
Article
ISSN
1600-5368

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The title compound, C 20 H 21 NO, was obtained by the reaction of indole-3-carbaldehyde with 4-tert-butylbenzyl chloride and recrystallization of the product from ethanol. The indole ring system is nearly planar and makes a dihedral angle of 74.45 (3) with the plane of the 4-tert-butylphenyl ring.

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Molecules of 5-bromo-1H-indole-3-carbaldehyde 3-methoxybenzoylylhydrazone, C 17 H 14 BrN 3 O 2 , are paired by aminocarbonyl hydrogen bonds over a center of inversion, and adjacent pairs are further linked by hydrogen bonds into ribbons.

3-Bromo-2-(4-bromo-2,5-dimethoxy­benz­yl
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In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking int

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In the title compound, C 18 H 20 N 4 O 2 , the triazole ring is twisted with respect to the two benzene rings with dihedral angles of 71.5 (3) and 67.3 (3) . N-HÁ Á ÁN hydrogen bonding occurs between neighboring molecules.

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The title compound, C 27 H 22 N 2 O 2 , was synthesized by the reaction of indole-3-carbaldehyde with 4-methoxyacetophenone and ammonium acetate in glycol under microwave irradiation. X-ray analysis reveals that NÐHÁ Á ÁN hydrogen bonds link the molecules into zigzag chains along [011].

2-(2-Benz­yloxy-3-methoxy­phen­yl)-1H-be
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In the title molecule, C 21 H 18 N 2 O 2 , all bond lengths and angles are normal. Weak intermolecular N-HÁ Á ÁN hydrogen bonds link the molecules into chains along the c axis. The crystal packing is further stabilized by van der Waals forces.