𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1-(3-Mesit­yl-3-methyl­cyclo­but­yl)-2-(piperidin-1-yl)ethanone

✍ Scribed by Çukurovalı, Alaaddin ;Özdemir, Namık ;Yılmaz, İbrahim ;Dinçer, Muharrem

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
263 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, C 21 H 31 NO, the cyclobutane ring is puckered, with a dihedral angle of 25.74 (6) . The mesityl and 2-N-piperidino-1-oxoethyl groups are in cis positions. The piperidine fragment adopts a chair conformation. Intermolecular C-HÁ Á ÁO interactions involving the piperidine CH group and the keto O atom lead to the formation of dimers, and intermolecular C-HÁ Á Á interactions involving the cyclobutane CH group and the benzene ring are responsible for the formation of a two-dimensional network.

📜 SIMILAR VOLUMES

2-Chloro-1-(3-mesityl-3-methylcyclo­buty
2-Chloro-1-(3-mesityl-3-methylcyclo­butyl)ethanone
✍ Demir, Sibel ;Dinçer, Muharrem ;Çukurovalı, Alaaddin ;Yılmaz, İbrahim 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 263 KB

The title compound, C 16 H 21 ClO, has a non-planar configuration. The crystal packing is mainly stabilized by intramolecular C-HÁ Á ÁO hydrogen-bonding interactions.

(2E)-2-(1-Methyl­piperidin-2-yl­idene)-1
(2E)-2-(1-Methyl­piperidin-2-yl­idene)-1-phenyl­ethanone
✍ Lemmerer, Andreas ;Michael, Joseph P. ;Pienaar, Daniel P. ;Sannasy, Desigan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 156 KB

Single-crystal X-ray study T = 173 K Mean (C-C) = 0.003 A Disorder in main residue R factor = 0.051 wR factor = 0.199 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

1-(3-Mesityl-3-methyl­cyclo­butyl)-2-(py
1-(3-Mesityl-3-methyl­cyclo­butyl)-2-(pyrrolidin-1-yl)­ethan-1-one
✍ Dinçer, Muharrem ;Özdemir, Namık ;Çukurovalı, Alaaddin ;Yılmaz, İbrahim ;Büyükgü 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 194 KB

In the title molecule, C 20 H 29 NO, the cyclobutane ring is puckered, with a dihedral angle of 19.8 (3) between the two planes. The pyrrolidine ring adopts an envelope conformation. There are intermolecular CÐHÁ Á ÁO and CÐHÁ Á Á% interactions.