✦ LIBER ✦

1-(3-Chlorophenyl)-3-pivaloylthiourea

✍ Scribed by Shoukat, Noreen ;Rauf, M. Khawar ;Bolte, Michael ;Badshah, Amin

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 835 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807028280

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

1-(2-Chlorophenyl)-3-pivaloylthiourea

✍ Shoukat, Noreen ;Khawar Rauf, M. ;Bolte, Michael ;Badshah, Amin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 207 KB

The title molecule, C 12 H 15 ClN 2 OS, shows the typical geometric parameters of a substituted thiourea derivative. There is an intramolecular N-HÁ Á ÁO hydrogen bond and the crystal packing is characterized by intermolecular N-HÁ Á ÁS hydrogen bonds.

1-(3-Bromophenyl)-3-pivaloylthiourea

✍ Sultana, Sarwat ;Khawar Rauf, M. ;Ebihara, Masahiro ;Badshah, Amin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 576 KB

The crystal structure of the title compound, C 12 H 15 BrN 2 OS, is composed of discrete molecules with bond lengths and angles quite typical for thiourea compounds of this class. The molecule exists in the solid state in its thione form with typical thiourea C-S and C-O bonds lengths, as well as sh

1-[3-(Trifluoromethyl)phenyl]-3-pival

1-[3-(Trifluoromethyl)phenyl]-3-pivaloylthiourea

✍ Shoukat, Noreen ;Khawar Rauf, M. ;Ebihara, Masahiro ;Badshah, Amin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 130 KB

The title compound, C~13~H~15~F~3~N~2~OS, shows an intramolecular N—H...O hydrogen bond and forms intermolecular N—H...S hydrogen bonds, generating a chain.

1-(2,4-Dichlorophenyl)-3-pivaloylthioure

1-(2,4-Dichlorophenyl)-3-pivaloylthiourea

✍ Saeed, Aamer ;Flörke, Ulrich 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 511 KB

## Experimental A freshly distilled solution of pivaloyl chloride (1.20 g, 10 mmol) in acetone (50 ml) was added dropwise to a suspension of potassium thiocyanate (0.97 g, 10 mmol) in acetone (30 ml) and the reaction mixture was refluxed for 30 min. After cooling to room temperature, a solution of

1-(4-Nitrophenyl)-3-pivaloylthiourea

✍ Sultana, Sarwat ;Khawar Rauf, M. ;Ebihara, Masahiro ;Badshah, Amin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 521 KB

In the title compound [systematic name: 1-(2,2-dimethylpropionyl)-3-(4-nitrophenyl)thiourea], C 12 H 15 N 3 O 3 S, the molecule exists in the thione form with typical thiourea C-S and C-O bonds, as well as shortened C-N bond lengths. The planes containing the thiourea N atoms form dihedral angles of

1-Benzoyl-3-(3-chlorophenyl)thiourea

✍ Rauf, M. Khawar ;Badshah, Amin ;Flörke, Ulrich ;Saeed, Aamer 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 183 KB