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ω-Transaminases for the synthesis of non-racemic α-chiral primary amines

✍ Scribed by Dominik Koszelewski; Katharina Tauber; Kurt Faber; Wolfgang Kroutil

Book ID
113932305
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
531 KB
Volume
28
Category
Article
ISSN
0167-7799

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Deracemisation of α-Chiral Primary Amine
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✍ Dominik Koszelewski; Dorina Clay; David Rozzell; Wolfgang Kroutil 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 1 views

## Abstract Racemic α‐chiral primary amines were deracemised to optically pure amines in up to >99 % conversion and >99 % __ee__ within 48 h. The deracemisation was a result of a stereoinversion of one amine enantiomer; the formal stereoinversion was achieved by a one‐pot, two‐step procedure: in th