μ-Oxalato-bis[chlorotripyridinecobalt(II)] pyridine disolvate
✍ Scribed by Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 225 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Co complex of the title compound, [Co 2 (C 2 O 4 )Cl 2 -(C 5 H 5 N) 6 ]ÁC 5 H 5 N, is located on a crystallographic centre of inversion. The solvent pyridine molecules are located on general positions. The Co centre is octahedrally coordinated by three pyridine ligands, one Cl atom and a chelating oxalate anion which bridges two Co centres.
📜 SIMILAR VOLUMES
In the centrosymmetric dinuclear title complex, [RuCl 2 ( 6 -C 6 H 6 )] 2 Á2CHCl 3 or [Ru 2 Cl 4 (C 6 H 6 ) 2 ]Á2CHCl 3 , accessible from RuCl 3 .nH 2 O and 1,3-cyclohexadiene, the benzene ligands are involved in slipped-parallelstacking interactions with neighbouring molecules, thus forming one-dim
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê R factor = 0.089 wR factor = 0.167 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.