Poly [[(dipyrido[3,2-
μ-Benzene-1,4-dicarboxylato-bis[chloro(dipyrido[3,2-a:2′,3′-c]phenazine)copper(II)]
✍ Scribed by Che, Guang-Bo ;Xu, Zhan-Lin ;Liu, Chun-Bo
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 196 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [Cu~2~Cl~2~(C~8~H~4~O~4~)(C~18~H~10~N~4~)~2~], the Cu^II^ atom is four-coordinated by two N atoms from one bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one Cl^−^ anion and one O atom from the benzene-1,4-dicarboxylate ligand. The complete benzene-1,4-dicarboxylate ligand is generated by inversion symmetry, leading to a dinuclear complex. Neighbouring molecules interact through π–π stacking, resulting in a two-dimensional supramolecular structure.
📜 SIMILAR VOLUMES
In the title compound, [Zn(C 8 H 4 O 4 )(C 18 H 10 N 4 )] 3n Á-2nC 18 H 10 N 4 , the three distinct Zn II atoms each exhibit a distorted cis-ZnN 2 O 4 octahedral coordination geometry arising from an N,N-bidentate dipyrido [3,3 0 -c]phenazine (C 18 H 10 N 4 ; DPPZ) molecule and two O,O-bidentate 1,4
In the title compound, [Co(C 8 H 4 O 4 )(C 18 H 10 N 4 )(H 2 O)] n , the Co II atom is six-coordinated by three O atoms from two benzene-1,4-dicarboxylate (1,4-BDC) dianions (one bidentate and one monodentate), one water molecule and two N atoms from a bidentate dipyrido[3,2-a:2 0 ,3 0 -c]phenazine
A new Zn II coordination polymer with intermolecular p-p interactions: catenapoly [[aqua(dipyrido[3,2-