μ-(2-Thioxo-1,3-dithiole-4,5-dithiolato)-bis{[tris(p-methoxyphenyl)phosphine]gold(I)}
✍ Scribed by Cerrada, E. ;Laguna, M. ;Villacampa, M. D.
- Book ID
- 119771172
- Publisher
- International Union of Crystallography
- Year
- 1998
- Tongue
- English
- Weight
- 313 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title complex, (C~7~H~12~NS)[Ni(C~3~S~5~)~2~], the dihedral angle between the thiazole ring of the cation and the plane of the anion is 8.0 (2)°. In the crystal structure, S...S intermolecular interactions between the anions form a distorted honeycomb structure parallel to the (002) plane, wi
In the title ion-pair compound, (C 12 H 11 FN)[Ni(C 3 S 5 ) 2 ], the Ni III atom is coordinated by four sulfur atoms of the two 2thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry. Weak C-HÁ Á ÁS interactions are found, resulting in a three-dimensional supramolecular network.