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η6:η6 Coordination of Tetraphenylborate to Ytterbium(II): A New Class of Lanthanoid ansa-Metallocenes

✍ Scribed by Glen B. Deacon; Craig M. Forsyth; Peter C. Junk


Book ID
102164596
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
182 KB
Volume
2005
Category
Article
ISSN
1434-1948

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop