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(η5-Pentamethylcyclopentadienyl)trimethyltitanium as a precursor for the syndiospecific polymerization of styrene

✍ Scribed by Homa Kucht; Andreas Kucht; Marvin D. Rausch; James C. W. Chien

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
287 KB
Volume
8
Category
Article
ISSN
0268-2605

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## Abstract The bimetallic ruthenium complex [(1,3,5‐__i__‐Pr~3~C~6~H~3~)Ru(μ‐Cl)~3~RuCl(C~2~H~4~)(PCy~3~)] has been synthesized by reaction of [(1,3,5‐__i__‐Pr~3~C~6~H~3~)RuCl~2~)]~2~ with one equivalent of PCy~3~ in the presence of ethylene. It can be used as a catalyst precursor for the controll