(η5-Pentamethylcyclopentadienyl)iridium(III) Complexes with η2-N,O andη2-P,S Ligands
✍ Scribed by Michael Gorol; Herbert W. Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 127 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The substitution reactions of [Re(CO)~5~X] (X = Cl, Br) with 2,6‐dihalo‐substituted nitrosobenzene derivatives C~6~H~2~YZ~2~NO (Y = H, Cl, Br; Z = Cl, Br) leads to the formation of dinuclear μ~2~‐η^2^‐__N__,__O__‐nitrosobenzene‐bridged complexes of the type [{(CO)~3~Re(μ‐X)}~2~ONC~6~H~2
led to the isolation of the complex [{η 5 :η 2 -C 5 Me 4 CH 2 CH 2 N(Me)CN(C 6 H 3 Me 2 )}-TiCl 2 ] (6) by insertion The new organometallic binuclear complexes [{Cp\* Ti(NEt 2 )} 2 (µ-NEt) 2 ] (1), [(Cp\*Ti) 2 (NMe 2 )(NHMe 2 )(µ-NMe)(µ-of one isocyanide molecule into the titanium-nitrogen bond in 5