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Disulfur Monoxide as Complex Ligand—Preparation and Molecular Structure of [(η5-C5Me5)Mn(CO)2(S2O)]

✍ Scribed by Prof. Dr. Max Herberhold; Dipl.-Chem. Bertram Schmidkonz; Prof. Dr. Manfred L. Ziegler; Dipl.-Chem. Thomas Zahn

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
240 KB
Volume
24
Category
Article
ISSN
0044-8249

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,