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η3-Diphosphavinylcarbene: A P2 Analogue of the Dötz Intermediate

✍ Scribed by Halil Aktas; J. Chris Slootweg; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma

Book ID
101537447
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
342 KB
Volume
121
Category
Article
ISSN
0044-8249

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Selective coupling of olefins and terminal acetylenes is nation sequence. [Ru(tp)(COD)Cl] and [Ru(tp){η 3 -(P,C,C)-Ph 2 PCH=CHC(Ph)=CH 2 }Cl] were the starting materials shown to be effected in the coordination sphere of Ru II by the successive intermediacy of vinylidene and which were treated with