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Synthesis, crystal and molecular structure of the “slipped” sandwich complex [Ni(η5-P3C2R2)(η3-P2C3R3)] (R = But)

✍ Scribed by Rainer Bartsch; Peter B. Hitchcock; John F. Nixon

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 253 KB
Volume: 373
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(89)85054-5

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## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C