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(η3-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands: Highly Active Catalysts for the Hydroamination of 1,3-Dienes

✍ Scribed by Tatsuya Minami; Hideyuki Okamoto; Shintaro Ikeda; Rika Tanaka; Fumiyuki Ozawa; Masaaki Yoshifuji


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
82 KB
Volume
40
Category
Article
ISSN
0044-8249

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Modular Bis(oxazoline) Ligands for Palla
✍ Miquel Angel Pericàs; Cristina Puigjaner; Antoni Riera; Anton Vidal-Ferran; Mont 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 286 KB 👁 1 views

New families of enantiopure bis(oxazolines) with 4,5-trans (5 a-g) or 4,5-cis (6 c) stereochemistry at the individual rings have been prepared in high yield. Their eta(3)-allyl palladium complexes (8 a-g, 9 c and 10) have been used as catalytic precursors in allylic alkylation reactions with excelle