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Evidence for the Intermediacy of (η3-Allyl)palladium Complexes in the Palladium-Catalyzed Acryloxylation of Cycloalkenes: Unexpected Oxidation of 1,5-Cyclooctadiene

✍ Scribed by Sylvaine Jabre-Truffert; Anne-Marie Delmas; Helena Grennberg; Björn Akermark; Bernard Waegell


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
307 KB
Volume
2000
Category
Article
ISSN
1434-193X

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The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h