Rate and Mechanism of the Reversible For
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Christian Amatore; Sophie Gamez; Anny Jutand
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Article
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2001
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John Wiley and Sons
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English
⚖ 155 KB
The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h