γ-1, 4 Addition of substituted methoxyallylcopper reagents to methylvinylketone

✍ Scribed by Jean-Franç¸ois Berrien; Marie-Noe¨lle Raymond; Fatima Zaari; Henri Moskowitz; Joe¨lle Rayrargue

• Book ID: 104261269
• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 196 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)00485-2

✦ Synopsis

Methoxyallylcopper reagents substituted in ot and/or 13 position of methoxy group reacted regiospecifically with MVK to give "{-1,4 adducts, i.e. ketoenolethers, y substituted methoxyallylcoppor reagents gave mixtures of y-1.4 and or-1.4 adducts