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Selective γ-1,4 addition of methoxyallylcopper to enone

✍ Scribed by Jean-François Berrien; Marie-Noëlle Raymond; Henri Moskowitz; Joëlle Mayrargue

Book ID
104260613
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
136 KB
Volume
40
Category
Article
ISSN
0040-4039

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γ-1, 4 Addition of substituted methoxyal
γ-1, 4 Addition of substituted methoxyallylcopper reagents to methylvinylketone
✍ Jean-Franç¸ois Berrien; Marie-Noe¨lle Raymond; Fatima Zaari; Henri Moskowitz; Jo 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 196 KB

Methoxyallylcopper reagents substituted in ot and/or 13 position of methoxy group reacted regiospecifically with MVK to give "{-1,4 adducts, i.e. ketoenolethers, y substituted methoxyallylcoppor reagents gave mixtures of y-1.4 and or-1.4 adducts