13-Enaminoketoesters, obtained by metal-catalyzed reaction between alkyl acetoacetates and alkyl cyanoformates, are useful starting materials for rapid access to I~-acetyl-dehydroaspartic acid derivatives which could be transformed into (+)-2-azetidinones beating a 1-hydrox'y-ethyl substituent throu
✦ LIBER ✦
βHydroxyaspartate Pathway: A New Route for Biosyntheses from Glyoxylate
✍ Scribed by KORNBERG, H. L.; MORRIS, J. G.
- Book ID
- 109626351
- Publisher
- Nature Publishing Group
- Year
- 1963
- Tongue
- English
- Weight
- 244 KB
- Volume
- 197
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/197456a0
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A new simple route for the synthesis of
✍
Carmela De Risi; Gian P. Pollini; Augusto C. Veronese; Valerio Bertolasi
📂
Article
📅
1999
🏛
Elsevier Science
🌐
French
⚖ 207 KB
ChemInform Abstract: A New Simple Route
✍
Carmela De Risi; Gian P. Pollini; Augusto C. Veronese; Valerio Bertolasi
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 33 KB
👁 2 views
ChemInform Abstract: A New Simple Route
✍
Carmela De Risi; Gian Piero Pollini; Augusto C. Veronese; Valerio Bertolasi
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 31 KB
👁 2 views
Asymmetric deuteration of N-acetyl-(Z)-α
✍
Akli Hammadi; André Ménez; Roger Genet
📂
Article
📅
1997
🏛
Elsevier Science
🌐
French
⚖ 377 KB
A novel approach to the synthesis of labelled (2H, ~H) peptides through the catalytic asymmetric reduction of AZTrp containing peptides, using rhodium complexes with chiral diphosphine ligands as the catalysts, is described. Ac-AZTrp-(L)-Phe-OMe is used as a model substrate to study this new route.