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β-Selective nucleoside analog synthesis from chlorofuranoses

✍ Scribed by Robert W. Scott; Darrell E. Fox; Dawnnica K. Williams

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 57 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01429-5

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✦ Synopsis

A method to form glycosyl linkages between nitrogen-containing heterocycles and appropriately protected furanoses is described. The method is highly beta-selective, operationally simple, and utilizes readily available reagents making the process amenable to scaleup. Representative examples of coupling between chlorofuranoses and purines or pyrrolopyrimidines are described.

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