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β-Pinene cationic polymerization using Keggin heteropolyacid catalysts

✍ Scribed by Hualong Zhu; Zuguang Liu; Taishun Zhang; Wei Zeng; Xinnan An; Fuhou Lei

Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
221 KB
Volume
99
Category
Article
ISSN
1878-5190

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Cationic polymerization of β-pinene with
Cationic polymerization of β-pinene with the AlCl3/SbCl3 binary catalyst: Comparison with α-pinene polymerization
✍ Jiang Lu; Masami Kamigaito; Mitsuo Sawamoto; Toshinobu Higashimura; Yun-Xiang De 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 410 KB

The polymerization of P-pinene with the A1Cl3/SbCl3 binary catalyst was investigated in toluene a t -40°C and was compared with that of a-pinene. The polymerization of P-pinene with AlC13 alone was very rapid and retarded on addition of SbC13, in sharp contrast to that of a-pinene where added SbC13