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Cationic polymerization of β-pinene and styrene

✍ Scribed by Charles Snyder; William McIver; Howard Sheffer

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
386 KB
Volume
21
Category
Article
ISSN
0021-8995

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Cationic polymerization of styrene(St) initiated by phosphorus trichloride(PC13) in nitrobenzene was carried out at 30 °. The initial rate was proportional to [St] 2 and [PCl3]. The overall activation energy was about 10.4 kcal/mole. The rate and the degree of polymerization were enhanced with incre