β-K2V3P4O17: A vanadium(IV) pyrophosphate with a layer structure
✍ Scribed by K.H. Lii; H.J. Tsai; S.L. Wang
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 483 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0022-4596
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A V(IV) tetraphosphate K 2 (VO) 2 P 4 O 13 has been synthesized for the first time, and crystals of this new phase can be grown in air. It crystallizes in the space group Pbca with a ؍ 22.181(2)A s , b ؍ 11.564(1)A s , c ؍ 9.948(1)A s . The original structure of this phase consists of corner s
A new vanadium (V) hydroxymonophosphate hydrate, K 3 (VO 2 ) 2 PO 4 PO 3 OH ' H 2 O, with a 99tape-like:: structure has been synthesized. This compound crystallizes in the space group P2 1 /c with a ؍ 5.099( 1) A > , b ؍ 29.168(3) A > , c ؍ 8.115(1) A > , ؍ 91.65(1)3. Its structure consists