𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Vanadium (V) Hydroxymonophosphate Hydrate with a “Tape-Like” structure: K3(VO2)2PO4PO3OH·H2O

✍ Scribed by A. Leclaire; M.M. Borel; B. Raveau

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
495 KB
Volume
163
Category
Article
ISSN
0022-4596

No coin nor oath required. For personal study only.

✦ Synopsis

A new vanadium (V) hydroxymonophosphate hydrate, K 3 (VO 2 ) 2 PO 4 PO 3 OH ' H 2 O, with a 99tape-like:: structure has been synthesized. This compound crystallizes in the space group P2 1 /c with a ‫؍‬ 5.099( 1) A > , b ‫؍‬ 29.168(3) A > , c ‫؍‬ 8.115(1) A > , ‫؍‬ 91.65(1)3. Its structure consists of [V 2 P 2 O 11 OH] ribbons built up of corner-sharing VO 5 pyramids, PO 4 , and PO 3 OH tetrahedra, interleaved with K ؉ ions and H 2 O molecules. In spite of its unidimensional character, this structure forms pentagonal tunnels. Relationships with frameworks involving tetragonal tunnels are studied. 2002 Elsevier Science (USA)

📜 SIMILAR VOLUMES

Hydrothermal Syntheses, Structures, and
Hydrothermal Syntheses, Structures, and Properties of Two New Potassium Vanadium Phosphates: K3(VO) (V2O3) (PO4)2(HPO4) and K3 (VO) (HV2O3) (PO4)2(HPO4)
✍ J.T. Vaughey; William T.A. Harrison; Allan J. Jacobson 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 417 KB

Two new potassium vanadium phosphates have been prepared and their structures have been determined from analysis of single crystal X-ray data. The two compounds, \(\mathrm{K}_{3}(\mathrm{VO})\left(\mathrm{V}_{2} \mathrm{O}_{3}\right)\) \(\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{HPO}_{4}\right)\

Ba2(VO2)(PO4)(HPO4)·H2O, a New Barium Va
Ba2(VO2)(PO4)(HPO4)·H2O, a New Barium Vanadium(V) Phosphate Hydrate Containing Trigonal Bipyramidal VO5Groups
✍ Zsolt Bircsak; William T.A. Harrison 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 301 KB

The hydrothermal synthesis, single crystal structure, and some physical properties of Ba 2 (VO 2 )(PO 4 )(HPO 4 ) • H 2 O, a new barium vanadium(V) phosphate hydrate, are reported. This phase is built up from one-dimensional chains of unusual VO 5 trigonal bipyramids and (H)PO 4 tetrahedra, fused to

A Vanadium (V) Monophosphate with a Tunn
A Vanadium (V) Monophosphate with a Tunnel Structure: KV2O4PO4
✍ F. Berrah; M.M. Borel; A. Leclaire; M. Daturi; B. Raveau 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 311 KB

A vanadium (V) monophosphate, KV 2 O 4 PO 4 , with an original tunnel structure has been synthesized. It crystallizes in the space group Pn2 1 a, with a ‫؍‬ 13.924(1) A s s , b ‫؍‬ 19.946(1) A s s , c ‫؍‬ 4.749(1) A s s . The [V 2 PO 8 ] framework consists of 903 3 oriented [V 2 O 8 ] pyramidal chai