## Abstract (1,3)‐β‐D‐Glucans form a group of biologically active biopolymers that exist in different structural organizations depending on the environmental conditions. The biological effect of (1,3)‐β‐D‐glucans is a core issue stimulating large research efforts of the molecular properties and the
✦ LIBER ✦
β-Homoalanyl PNAs: Synthesis and Indication of Higher Ordered Structures
✍ Scribed by Ulf Diederichsen; Harald W. Schmitt
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 215 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
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✦ Synopsis
Self-pairing complexes with extraordinarily high stability are formed by β-PNAs with four to six units of the nucleo-β-amino acid 1. The key step in the synthesis is a Mitsunobu reaction between a β-homoserine and a purine derivative.
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The effects of high energy ultrasound and slightly raised temperature combined with the denaturing action of dimethylsulphoxide on the molecular weight and higher-order structure of hyaluronans and some &(1+ 3)-glucans were studied by means of size exclusion chromatography (SEC) technique. Some expe