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β - Diketones as Key Compounds in Free-Radical Polymerization by Enzyme-Mediated Initiation

✍ Scribed by Teixeira, Didier; Lalot, Thierry; Brigodiot, Maryvonne; Maréchal, Ernest

Book ID
120541641
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
89 KB
Volume
32
Category
Article
ISSN
0024-9297

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A relatively fast method for determining the initial rate of polymerization from the maximum of isothermal thermograms ("Vp. max method") is described. The method was verified for the polymerization of methyl methacrylate in dimethylformamide. The initial rates and overall rate constants agree excel