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β-diketone interactions: Part 5. Solvent effects on the keto ⇋ enol equilibrium

✍ Scribed by John Emsley; Neville J. Freeman


Book ID
103210146
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
751 KB
Volume
161
Category
Article
ISSN
0022-2860

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📜 SIMILAR VOLUMES


Substituent effects in keto-enol tautome
✍ M. Bassetti; G. Cerichelli; B. Floris 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 437 KB

The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h