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Solvent effects on the energetic parameters and chemical reactivity in the keto–enol tautomeric equilibrium of substituted carbonyl compounds

✍ Scribed by Nelly González-Rivas; Andrés Cedillo


Book ID
116380206
Publisher
Elsevier
Year
2012
Tongue
English
Weight
772 KB
Volume
994
Category
Article
ISSN
2210-271X

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📜 SIMILAR VOLUMES


Substituent effects in keto-enol tautome
✍ M. Bassetti; G. Cerichelli; B. Floris 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 437 KB

The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h