β-Diketonate, β-Ketoiminate, and β-Diiminate Complexes of Difluoroboron
✍ Scribed by Felipe P. Macedo; Chengeto Gwengo; Sergey V. Lindeman; Mark D. Smith; James R. Gardinier
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 684 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
Unsymmetrically substituted//-diketones, RCOCH2COR' (R and R'= aryl) have been synthesized and used to prepare their monothio-fi-diketone derivatives. Because of the similar basicities of the carbonyl oxygen due to the electronic effects of the R and R' groups, a mixture of the monothio-fl-diketones
The bulky β-diiminate ligands [(2,6-C 6 H 3 X 2 )NC(Me)CHC(-Me)N(2,6-C 6 H 3 X 2 )] -(X = Me, L Me ; X = Cl, L Cl ) have been found to be effective in stabilizing low coordination numbers (CN) in Rh and Ir complexes. The 14-e complex L Me Rh(COE) (COE = cyclooctene) has a three-coordinate T-shaped R