β-Diethoxyphosphorylpropionic acid, a convenient reagent for the synthesis of β,δ - unsaturated amides
✍ Scribed by Tomasz Janecki; Ryszard Bodalski
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 218 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
It has been shown that over-all conversions of carbonyl compounds to olefins, similar to the well known "Wittig" reaction, could be effected using silicon-substituted carbanions 1 . Recently, an alkyl lithiomethylacetate was reported to be an excellent reagent for the synthesis of a,%-unsaturated ca
A novel strategy is described for the synthesis of l~,¥-unsaturated aldehydes which are the useful synthons for the synthesis of arachidonic acid and other eicosanoid products. These 13,y-unsaturated aldehydes have been used in the total synthesis of arachidonic acid.