𝔖 Bobbio Scriptorium
✦   LIBER   ✦

α'β-Elimination and wittig rearrangement of the carbanion from benzyl cyclooctyl ether

✍ Scribed by Hugues d'Orchymont; Maurice P. Goeldner; Jean-François Biellmann

Book ID
104220700
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
190 KB
Volume
23
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

No trans-cyclooctene was detected and the deuterium labeling pattern shows that no isomarisation of trans to the cis-cyclooctene seemed to occur.

📜 SIMILAR VOLUMES

Olefinic stereoselection in the [2,3]-Wi
Olefinic stereoselection in the [2,3]-Wittig rearrangement of α,β-disubstituted allylic ethers forming trisubstituted olefins
✍ Katsuhiko Tomooka; Tatsuya Igarashi; Naoyuki Kishi; Takeshi Nakai 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 237 KB

The F\_,/Z-selectivities in the [2,3]-Wittig rearrangements of secondary 13-(methyl or silyl)allylic ethers are shown to depend critically on the nature of groups on the carbanion terminus, thereby permitting elucidation of the structural requirements for attaining high Z-selectivity.