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α-Siloxyamides from a carbamoylsilane and carbonyl compounds

✍ Scribed by Robert F Cunico

Book ID: 104232218
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 80 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02177-3

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✦ Synopsis

The reaction of a carbamoylsilane with aldehydes or ketones affords a-siloxyamides. The addition reaction is catalyzed by fluoride ion (TBAT, 25-50°C), but proceeds in the absence of catalyst at higher temperatures (50-100°C).

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