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α-Aminoamides from a Carbamoylsilane and Aldehyde Imines.

✍ Scribed by Jianxin Chen; Robert F. Cunico


Book ID
101952451
Publisher
John Wiley and Sons
Year
2004
Weight
117 KB
Volume
35
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES


α-Siloxyamides from a carbamoylsilane an
✍ Robert F Cunico 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 80 KB

The reaction of a carbamoylsilane with aldehydes or ketones affords a-siloxyamides. The addition reaction is catalyzed by fluoride ion (TBAT, 25-50°C), but proceeds in the absence of catalyst at higher temperatures (50-100°C).

α-(Dimethylamino)amides from a carbamoyl
✍ Jianxin Chen; Robert F. Cunico 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 84 KB

The reaction of a carbamoylsilane with iminium salts derived from aldehydes lacking a-hydrogens affords the title compounds.