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α-N-acyliminium ion - 2-bromoalkene cyclizations.

✍ Scribed by Jean-Pierre Gesson; Jean-Claude Jacquesy; Didier Rambaud


Book ID
108371578
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
602 KB
Volume
49
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


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## Abstract For Abstract see ChemInform Abstract in Full Text.

Completely regioselective α-acyliminium
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Intramolecular reactions of a-acyliminium ions with ally1 and propargyl silanes occur under the influence of trifluoroacetic acid, to afford in high yield and with complete reqioselectivity bridgehead nitrogen bicyclic compounds z-8.