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Furan-Terminated N-Acyliminium Ion Initiated Cyclizations in Alkaloid Synthesis∇

✍ Scribed by Tanis, Steven P.; Deaton, Melissa V.; Dixon, Lisa A.; McMills, Mark C.; Raggon, Jeffrey W.; Collins, Mark A.


Book ID
115442123
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
504 KB
Volume
63
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Studies Toward the
✍ W. G. BEYERSBERGEN VAN HENEGOUWEN; H. HIEMSTRA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

Studies Toward the Total Synthesis of the Oxindole Alkaloid Gelsedine: An Efficient Allene-Terminated N-Acyliminium Ion Cyclization. -The preparation of the advanced synthetic intermediate (VII) in the projected synthesis of enantiopure ent-gelsedine is reported. The use of the inexpensive (S)-enan