α-Hydroxy Carboxylic Acids (I) and (II) as Ligands for Enantioselective Addition Reactions of Organoaluminum Reagents to Aromatic and Aliphatic Aldehydes.
✍ Scribed by Tomasz Bauer; Joanna Gajewiak
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 29 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract No base is required for the Mg(II)‐catalyzed conjugate addition of nitromethane to α′‐hydroxy enones in the presence of molecular sieves. Good enantioselectivities are attained using 3 or 4 Å MS and about 10 mol % of Mg(OTf)~2~‐chiral bisoxazoline complexes. Elaboration of the adducts t
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v