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Catalytic Enantioselective Conjugate Addition of Nitromethane to α′-Hydroxy Enones as Surrogates of α,β-Unsaturated Carboxylic Acids and Aldehydes.

✍ Scribed by Claudio Palomo; Raquel Pazos; Mikel Oiarbide; Jesus M. Garcia

Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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Organocatalysis [1] has expanded widely within the last few years, since the rediscovery of the proline-catalyzed aldol reaction. [2] Since then, several different methods, such as fluorination, [3] chlorination, [4] bromination, [5] sulfenylation, [6] amination, [7] and Mannich reactions, [8] have