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α-Deprotonated allyl ethers: Conformational mobility and conformational preferences

✍ Scribed by Christian Margot; Paola Maccaroni; Frédéric Leroux; Manfred Schlosser

Book ID: 108379094
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 375 KB
Volume: 54
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)00774-1

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## Abstract The PMR spectrum of 2‐bromo‐4,6‐dinitrophenyl 2′‐naphthyl ether (**1**) is consistent with the preferential adoption of a twist conformation (**1a**) in which the 6‐nitro group and the 1′‐hydrogen are located __endo__ to the ether link. This preference is explained by the formation of a