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1-(Triphenylmethyl)allyl potassium :conformational preference and [1,2]-rearrangement

✍ Scribed by Etienne Moret; Jürg Fürrer; Manfred Schlosser


Book ID
104203619
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
873 KB
Volume
44
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES


Orbital and Conformational Preferences i
✍ B.A. Dellacoletta; H. Shechter 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 266 KB

The stereochemistry of rearrangement of substituted 1-phenyl-1-propylidenes to trans and cis-propenylbenzenes is substituent dependent. --A fascinating aspect of carbenes is the possible discrimination in the interactions of their non-bonded orbitals with substituents.l It has been suggested that e