Orbital and Conformational Preferences i
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B.A. Dellacoletta; H. Shechter
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Article
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1979
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Elsevier Science
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French
⚖ 266 KB
The stereochemistry of rearrangement of substituted 1-phenyl-1-propylidenes to trans and cis-propenylbenzenes is substituent dependent. --A fascinating aspect of carbenes is the possible discrimination in the interactions of their non-bonded orbitals with substituents.l It has been suggested that e